Cobalt Gluconate Anhydrous Dihydrate SDS MSDS of Manufacturers & Exporters
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Cobalt Gluconate Anhydrous CAS Number 71957-08-9 Anhydrous
Cobalt Gluconate Dihydrate CAS Number 1809162-99-9 Dihydrate
Cobalt Gluconate SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 20-July-22
Section 1: Product and Company Identification
Product Name & Other Names: Cobalt gluconate or Gluconic acid cobalt salt.
CAS No.: 71957-08-9 and [Dihydrate (1809162-99-9)]
EINECS, EC Number: 276-206-1
Molecular Weight: 449 Anhydrous
Chemical Formula: C12H22CoO14 Anhydrous
Relevant uses and uses advised against (if any): Laboratory chemicals, Manufacture of substances
Supplier: As per letterhead
Section 2: Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Acute toxicity, Oral (Category 4), H302
Skin sensitization (Category 1), H317
Eye irritation Category 2A, H319
Respiratory sensitization (Category 1), H334
Germ cell mutagenicity (Category 2), H341
Carcinogenicity (Category 2), H351
Chronic aquatic toxicity (Category 1), H410
Labeling according to GHS & Regulation (EC) No 1272/2008
GHS Label Elements
Irritant |
GHS Label Elements
Health Hazard |
GHS Label Elements
Marine Pollutant |
Signal Words: Danger
Hazard statements:
H302: Harmful if swallowed.
H317: May cause an allergic skin reaction.
H319: Causes serious eye irritation.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H351: Suspected of causing cancer.
H410: Very toxic to aquatic life with long lasting effects.
Precautionary statements:
P202: Do not handle until all safety precautions have been read and understood.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264 Wash thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P362: Take off contaminated clothing and wash before reuse.
P330 : Rinse mouth
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell.
P302+P352: IF ON SKIN: Wash with plenty of soap and water.
P304+341: IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P308+313: IF exposed or concerned: Get medical advice/attention.
P337+313: If eye irritation persists get medical advice/attention.
P342+311: If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
Xn Harmful
C Corrosive
N Dangerous for Environment
Risk Phrase:
R38 Irritating to skin.
R45 May cause cancer
R20/21/22 Harmful by inhalation, in contact with skin and if swallowed
R 42/43 May cause sensitization by inhalation and skin contact.
R 49 May cause cancer by inhalation.
R 51/53 Toxic to aquatic organisms, may cause long term adverse effects in the aquatic environment.
Section 3: Composition / Information on Ingredients
Product Name & Other Names: Cobalt gluconate or Gluconic acid cobalt salt.
CAS No.: 71957-08-9 and [Dihydrate (1809162-99-9)]
EINECS, EC Number: 276-206-1
Section 4: First Aid Measures
Always seek medical attention after first aid measures are provided
Eyes: Immediately flush eyes with excess water for 15 minutes, lifting lower and upper eyelids occasionally.
Skin: Immediately flush skin with excess water for 15 minutes while removing contaminated clothing.
Ingestion: Call Emergency Medical immediately. Rinse mouth with cold water. Give victim 1-2 cups of water or milk to drink. Induce vomiting immediately.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration.
Section 5: Fire Fighting Measures
It is non-flammable solid. When heated to decomposition, emits acrid fumes.
Protective equipment and precautions for firefighters: Use foam or dry chemical to extinguish fire. Firefighters should wear full fire fighting turn-out gear and respiratory protection. Cool container with water spray. Material is not sensitive to impact or static discharge.
Special hazards arising from the substance: Fumes, cobalt oxides.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes.
Section 6: Accidental Release Measures
Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Do not inhale dust, vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.
Section 7: Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents.
Section 8: Exposure Controls / Personal Protection
Exposure guidelines: Contains no substances with occupational exposure limit values.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.
Section 9: Physical and Chemical Properties
Physical state and appearance: Solid. (Crystals or Powder.)
Odor: Odorless.
Odor threshold: Not available.
pH: Not available.
Relative density: Not available.
Melting Point: >300C
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: No information found.
Decomposition temperature: No information found.
Upper/lower flammability or explosive limits: No information found.
Vapor pressure: No information found.
Vapor density: No information found.
Evaporation rate: No information found.
Flammability (solid, gas): No information found.
Partition coefficient: n-octanol/water: No information found.
Solubility: Soluble in water.
Viscosity: No information found.
Molecular Weight: 449 Anhydrous
Chemical Formula: C12H22CoO14 Anhydrous.
Section 10: Stability and Reactivity
Avoid heat and ignition sources.
Stability: Stable under normal conditions of use and storage.
Incompatibility: Heat and strong oxidizing agents.
Shelf life: Indefinite if stored properly.
Hazardous Decomposition Products: Fumes, cobalt oxides.
Hazardous Polymerization: Has not been reported.
Section 11: Toxicology Information
LD50 [oral, rat]; Not available.
Carcinogenicity: Group 2B: Possibly carcinogenic to humans by IARC.
Teratogenic Effects: No information found.
Mutagenic Effects: No information found.
Developmental Toxicity: No information found.
Reproductive Effects: No information found.
Section 12: Ecological Information
Toxicity to fish: Not available.
Ecotoxicity (aquatic and terrestrial): Contains a heavy metal – toxic to terrestrial and aquatic plants and animals. Do not release to environment.
Persistence and Degradability: Unlikely to persist due to water solubility.
Mobility: Likely to be mobile due to water solubility.
Bioaccumulation/ Accumulation: No information found.
Results of PBT and vPvB assessment: No information found.
Section 13: Disposal Considerations
Check with all applicable local, regional, and national laws and regulations.
Section 14: Transport Information
DOT USA and ADR/RID Europe:
UN-No: UN3288
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Proper technical name: Cobalt Gluconate
Hazard Class: 6.1; Packing Group: III
TDG:
UN-No: UN3288
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Proper technical name: Cobalt Gluconate
Hazard Class: 6.1; Packing Group: III
IATA
UN-No: UN3288
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Proper technical name: Cobalt Gluconate
Hazard Class: 6.1; Packing Group: III
IMDG/IMO
UN-No: UN3288
Proper Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
Proper technical name: Cobalt Gluconate
Hazard Class: 6.1; Packing Group: III
Section 15: Regulatory Information
USA:
SARA 311/312 Hazards: Acute Health Hazard, Chronic Health Hazard. See section 2.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
Section 16: Other Information
European Labeling in Accordance with EC Directives:
H302: Harmful if swallowed.
H317: May cause an allergic skin reaction.
H319: Causes serious eye irritation.
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H351: Suspected of causing cancer.
H410: Very toxic to aquatic life with long lasting effects.
Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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Specifications of Cobalt Gluconate Anhydrous Dihydrate BP Ph Eur EP JP USP NF IP ACS Analytical Reagent FCC Food grade Manufacturers |
