Crystal Clear Products Ankleshwar India
Plot No-C1-1031-9, GIDC Estate, Panoli, Ankleshwar, Gujarat - 393002. India
Telephone Mobile: 91-7506449333; e-mail: info@crystalclearproducts.org

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Basic Copper Carbonate and Copper Carbonate SDS MSDS of Manufacturers & Exporters

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Copper Carbonate Exporters Basic Copper Carbonate Suppliers Manufacturers
Copper Carbonate CAS Number 1184-64-1
Basic Copper Carbonate CAS Number 12069-69-1

Copper Carbonate and Basic Copper Carbonate SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet
10-July-22

1. Product Identification

Product Name & Other Names: Copper Carbonate and Basic Copper Carbonate.
CAS No.: 1184-64-1 and (12069-69-1 for Basic Copper Carbonate)
EINECS EC Number: 214-671-4 or 231-325-8 and (235-113-6 for Basic Copper Carbonate)
Molecular Weight: 123.55 and (221.12 for Basic Copper Carbonate)
Chemical Formula: CuCO3 and [CuCO3-Cu(OH)2 for Basic Copper Carbonate]
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008:

Acute toxicity, Oral Category 4, H302
Skin irritation Category 2, H315
Serious eye damage/eye irritation Category 2A, H319
Hazardous to the aquatic environment, acute hazard Category 2, H401

Labeling according to GHS & Regulation (EC) No 1272/2008

GHS Label Elements
Irritant
Irritant

Signal Words: Warning

Hazard statements:
H302: Harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H401: Toxic to aquatic life.

Precautionary statements:
P261: Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P262: Do not get in eyes, on skin, or on clothing.
P264: Wash skin thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P330: Rinse mouth
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+P352: IF ON SKIN: Wash with soap and water.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314: Get Medical advice/attention if you feel unwell.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P337+P313: If eye irritation persists: Get medical advice/ attention.

Classification according to EU Directives 67/548/EEC or 1999/45/EC:
Hazard Symbol:
Xn: Harmful
Xi: Irritant
Risk Phrase:
R22: Harmful if swallowed.
R 36/38 Irritating to eyes and skin.
R52 Harmful to aquatic organisms.

3. Composition/Information on Ingredients

Product Name & Other Names: Copper Carbonate and Basic Copper Carbonate.
CAS No.: 1184-64-1 and (12069-69-1 for Basic Copper Carbonate)
EINECS EC Number: 214-671-4 or 231-325-8 and (235-113-6 for Basic Copper Carbonate).

4. First Aid Measures

Always seek medical attention after first aid measures are provided

Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar, tie, belt, or waistband. If large amounts were swallowed, get medical advice.
Skin Contact: Immediately flush skin with plenty of soap and water for at least 15 minutes. Remove contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention if irritation develops.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting upper and lower eyelids occasionally. Get medical attention if irritation persists.

5. Fire Fighting Measures

Fire: Not considered to be a fire hazard. Irritating fumes, carbon oxides and copper oxide may form in fires.
Explosion: Not considered to be an explosion hazard.
Fire Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide. Use means suitable for extinguishing surrounding fire. Avoid a solid water stream as it may scatter and spread fire. Water spray may be useful in cooling equipment exposed to heat and flame.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode.

6. Accidental Release Measures

Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill:
Do not inhale dust, vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law.

7. Handling and Storage

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray.Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, strong acids, and bases.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: USA - ACGIH TLV and USA. NIOSH: TWA: 1 mg/m3.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn. If oil particles (e.g. lubricants, cutting fluids, glycerin, etc.) are present, use a NIOSH type R or P filter.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.

9. Physical and Chemical Properties

Appearance: Copper green crystal or powder.
Odor: Not available.
Odor threshold: Not available.
pH: Not available.
Relative density: Not available.
Melting point/freezing point: Not available.
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: No information found.
Decomposition temperature: No information found.
Upper/lower flammability or explosive limits: No information found.
Vapor pressure: No information found.
Vapor density: No information found.
Evaporation rate: No information found.
Flammability (solid, gas): No information found.
Partition coefficient: n-octanol/water: No information found.
Solubility: Insoluble in water.
Viscosity: No information found.
Molecular Weight: 123.55 and (221.12 for Basic Copper Carbonate)
Chemical Formula: CuCO3 and [CuCO3-Cu(OH)2 for Basic Copper Carbonate]

10. Stability and Reactivity

Stability: Stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Burning may produce fumes, carbon oxides and copper oxide.
Hazardous Polymerization: Will not occur.
Incompatibilities: Acids, caustic alkalis and strong oxidizing agents.
Conditions to Avoid: Heat, incompatibles.

11. Toxicological Information

Acute toxicity: LD50 Oral - Rat - 1350 mg/kg (Basic Copper Carbonate)
Carcinogenicity: The product is not classed as carcinogen by IARC, ACGIH, NTP, OSHA.
Mutagenic Effects: No information found.
Reproductive Effects: No information found.
Developmental Effects: No information found.

12. Ecological Information

Toxicity to fish: No information found.
Environmental Toxicity: Harmful to aquatic life. Avoid release to the environment.
Persistence and degradability: No information found.
Mobility in soil: No information found.

13. Disposal Considerations

Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility.

14. Transport Information

DOT USA &ADR/RID Europe: No information found.
IMDG
: No information found.
IATA: No information found.

15. Regulatory Information

SARA 311/312: See section 2.
California Proposition 65: Not listed.

16. Other Information

Disclaimer:
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Our company provides this MSDS sheet in good faith but makes no representation as to its comprehensiveness or accuracy. This SDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. The above information has been compiled from various sources and has the possibility of discrepancy and being out-dated information. Individuals receiving the information must exercise their independent judgment and do further search in determining its appropriateness for a particular purpose. In no case shall our company be liable to loss or damages by the product user.
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Specifications of Basic Copper Carbonate and Copper Carbonate BP Ph Eur EP JP USP NF IP ACS Analytical Reagent FCC Food grade Manufacturers

Crystal Clear Products and the group companies are manufacturing chemicals since several decades. We have automatic vacuum operated titanium evaporators and SS316 equipments to produce top grade of chemical products. We have toll manufacturers and representatives in China, UAE, Europe, Canada & USA and agents & customers in all countries like USA, Canada, Europe, UAE, South Africa, Tanzania, Kenya, Egypt, Nigeria, Uganda, Turkey, Mexico, Brazil, Chile, Argentina, Bangkok Thailand, Kaula Lumpur Malaysia, Dubai UAE etc. & sales representative in Chicago, Houston New York & Los Angeles, USA. Associated units are FDA-GMP certified, Halal and/or Kosher certified, REACH registered, ISO-9001, ISO-22000 HACCP certified, Crisil Rated.

Contact Basic Copper Carbonate and Copper Carbonate IP BP Ph Eur EP JP USP NF ACS Analytical Reagent FCC Food Grade manufacturers exporters at:

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Crystal Clear Products
Plot No-C1-1031-9, GIDC Estate, Panoli, Ankleshwar, Gujarat - 393002. India
Telephone Mobile: 91-7506449333; e-mail: info@crystalclearproducts.org

e-mail: info@crystalclearproducts.org

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