Sulphur or Sulfur Precipitated Sublimed Powder Granules Pellets Rolls Sticks SDS MSDS of Manufacturers & Exporters
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Sulphur or Sulfur Precipitated Sublimed Powder Granules Pellets Rolls Sticks CAS Number 7704-34-9
Sulfur Powder Granules Rolls SDS, Safety Data Sheet
MSDS, Material Safety Data Sheet 08-Aug-22
SECTION 1. PRODUCT IDENTIFICATION
Product Name & Other Names: Sulfur Powder Granules Rolls.
CAS Number: 7704-34-9
EINECS EC Number: 231-722-6
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Supplier: As per the letterhead.
SECTION 2. HAZARDS IDENTIFICATION
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Flammable solids (Category 1), H228
Acute toxicity, oral (Category 4), H302
Acute toxicity, inhalation (Category 4), H332
Skin corrosion/irritation (Category 2), H315
Serious eye damage (Category 1), H318
Specific target organ toxicity, single exposure; Respiratory tract irritation (Category 3), H335
Hazardous to the aquatic environment, acute hazard (Category 2), H401
Labeling according to GHS USA & Regulation (EC) No 1272/2008
GHS Label Elements
Flammable Solids |
GHS Label Elements
Irritant |
Signal Words: Danger
Hazard statements:
H228: Flammable solid.
H315: Causes skin irritation.
Precautionary statements:
P210: Keep away from heat/sparks/open flames/hot surfaces - No smoking.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/light/---/equipment.
P261: Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P262: Do not get in eyes, on skin, or on clothing.
P264 Wash skin thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P330: Rinse mouth.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+P352: IF ON SKIN: Wash with soap and water.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313: If eye irritation persists: Get medical advice/ attention.
P370+378: In case of fire: Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide for extinction.
SECTION 3. COMPOSITION / INFORMATION ON INGREDIENTS
Product Name & Other Names: Sulfur Powder Granules Rolls.
CAS Number: 7704-34-9
EINECS EC Number: 231-722-6
SECTION 4. FIRST AID MEASURES
Always seek medical attention after first aid measures are provided.
Eye Contact: Do not allow victim to rub eye (s). Let the eye (s) water naturally for a few minutes. If particle/dust does not dislodge, flush with lukewarm, gently flowing water for 5 minutes or until particle/dust is removed, while holding eyelid (s) open. If irritation persists, obtain medical attention. DO NOT attempt to manually remove anything stuck to the eye.
Skin Contact: Remove contaminated clothing, shoes, and leather goods (e.g., watchbands, belts). Quickly and gently blot or brush away excess chemical. Wash gently and thoroughly with lukewarm gently flowing water and non-abrasive soap for 5 minutes. If irritation persists, repeat flushing. Obtain medical advice. Completely decontaminate clothing, shoes and leather goods before reuse or else discard.
Inhalation: If symptoms are experienced, remove source of contamination or move victim to fresh air. Obtain medical advice.
Ingestion: Never give anything by mouth if victim is rapidly losing consciousness or is unconscious or convulsing. Have victim rinse mouth thoroughly with water. DO NOT INDUCE VOMITING. Have victim drink 2 – 8 oz. (60 – 240 ml) of water.
SECTION 5. FIRE FIGHTING MEASURES
Fire and Explosion Hazards: Flammable Solids.
Extinguishing Media: Use means of extinction appropriate for the surrounding fire conditions such as water spray, carbon dioxide, dry chemical, or foam.
Extinguishing Media Not recommended: Avoid using solid water jet as it may scatter the fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At elevated temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Procedures for Cleanup: Stop release, if possible, to do so safely. Contain spill, isolate hazard area, and deny entry. Sweep up or vacuum. Place contaminated material in suitable, labeled containers for final disposal.
Personal Precautions: Gloves and coveralls or other protective clothing are recommended for persons responding to an accidental release. Close-fitting safety goggles may be necessary in some circumstances to prevent eye contact.
Environmental Precautions: Contamination of soil and water should be prevented. Keep spillage from entering soil, streams, or sewers.
SECTION 7. HANDLING AND STORAGE
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Keep container tightly closed. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.).
Conditions for safe storage, including any incompatibilities: Keep away from sources of ignition - No smoking. Take measures to prevent the build-up of electrostatic charge. Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. generating dust and the release of dust into the workplace. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Do not store with incompatible materials like oxidizing agents.
SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Limits: This product does not contain any hazardous materials with occupational exposure limits established by the region-specific regulatory bodies.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full-face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: It is yellow solid.
Odor: Odorless to mild odor.
Odor threshold: No data found.
pH: No data found.
Relative density: around 2.07
Melting point/freezing point: 118C - 120C.
Initial boiling point and boiling range: No data found.
Flash point: No data found.
Auto-ignition temperature: No information found.
Decomposition temperature: No information found.
Upper/lower flammability or explosive limits: No information found.
Vapor pressure: No information found.
Vapor density: No information found.
Evaporation rate: No information found.
Flammability (solid, gas): No information found.
Partition coefficient: n-octanol/water: No information found.
Solubility(ies): Insoluble in water.
Viscosity: No information found.
SECTION 10. STABILITY AND REACTIVITY
Stability and Reactivity: Stable and not considered reactive under normal temperatures and pressures. Hazardous polymerization or runaway reactions will not occur.
Incompatibilities: Oxidizing agents. Avoid excessive heat. Avoid moisture. Heat, flames, and sparks.
Hazardous Decomposition Products: High temperature operations will generate sulfur oxide fume. Under such conditions, sulfur dioxide will also be generated and can cause respiratory distress.
SECTION 11. TOXICOLOGICAL INFORMATION
LD50 Oral - Rat - male and female: > 2.000 mg/kg.
LC50 Inhalation - Rat - male and female - 4 h: > 5,43 mg/l
LD50 Dermal - Rat - male and female: > 2.000 mg/kg
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Teratogenic Effects: No information found.
Mutagenic Effects: No information found.
Developmental Toxicity: No information found.
Reproductive Effects: No information found.
SECTION 12. ECOLOGICAL INFORMATION
Toxicity to fish: No data found.
Toxicity to daphnia and other aquatic invertebrates: flow-through test EC50 - Daphnia dubia (water flea) - 5.55 mg/l - 48 h
Mobility: No information found.
Bioaccumulation/ Accumulation: No information found.
Results of PBT and vPvB assessment: No information found.
SECTION 13. DISPOSAL CONSIDERATIONS
Do not wash the material down drain. Put uncontaminated material back into the process if possible. Place contaminated material in suitable, labeled containers for disposal.
SECTION 14. TRANSPORT INFORMATION
Land Transport DOT USA, TDG Canada & ADR/RID Europe:
UN Number: 1350
UN proper shipping name: Sulfur.
Transport hazard class(es): 4.1; Packaging group: III
Air Transport ICAO/IATA:
UN Number: 1350
UN proper shipping name: Sulfur.
Transport hazard class(es): 4.1; Packaging group: III
Sea Transport IMDG/IMO:
UN Number: 1350
UN proper shipping name: Sulfur.
Transport hazard class(es): 4.1; Packaging group: III.
SECTION 15. REGULATORY INFORMATION
USA Regulations:
SARA 311/312 Hazards: See section 2.
California Prop. 65 Components: Not listed.
SECTION 16 - ADDITIONAL INFORMATION
DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources, and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules, or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a professionally trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. Specifications of Sulphur or Sulfur Precipitated Sublimed Powder Granules Pellets Rolls Sticks BP Ph Eur EP JP USP NF IP ACS Analytical Reagent FCC Food grade Manufacturers |
