Acetic Acid Solution n Acetic Acid Glacial SDS MSDS of Manufacturers & Exporters
Please check Acetic Acid Solution n Acetic Acid Glacial USP NF ACS BP Ph Eur EP JP IP Analytical reagent FCC Food grade Manufacturers our associates world class FDA-GMP approved, ISO-9001 Certified facility Anmol Chemicals
Acetic Acid Solution n Acetic Acid Glacial CAS Number 64-19-7
Glacial Acetic Acid SDS, Safety Data Sheet
MSDS, Material Safety Data Sheet 13-Aug-22
Section 1 - Chemical Product and Company Identification
Product Name & Other Names: Glacial Acetic or Ethanoic acid or Ethylic acid or Methanecarboxylic acid or Vinegar.
CAS#: 64-19-7
EINECS EC Number: 200-580-7
Molecular Formula: CH3COOH
Molecular Weight: 60.05
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.
Section 2 - Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Flammable liquids (Category 3) H227
Skin corrosion/irritation (Category 1A, B, C) H314
Acute aquatic toxicity (Category 3) H402
Labeling according to GHS & Regulation (EC) No 1272/2008
GHS Label Elements
Combustible Liquid |
GHS Label Elements
Corrosive |
Signal Words (GHS-USA): Danger
Hazard statements (GHS-USA):
H227: Combustible liquid.
H314: Causes severe skin burns and eye damage.
H402: Harmful to aquatic life.
Precautionary statements (GHS-USA):
P210: Keep away from heat, sparks, open flames, hot surfaces. - No smoking.
P260: Do not breathe mist, vapors, spray.
P264: Wash exposed skin thoroughly after handling.
P280: Wear protective clothing, protective gloves, eye protection, face protection.
P301+P330+P331: IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303+P361+P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+P340: IF INHALED: remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314: Get Medical advice/attention if you feel unwell.
P337+ P313: If eye irritation persists: Get medical advice/ attention.
P370+P378: In case of fire: Use carbon dioxide (CO2), powder, alcohol-resistant foam for extinction.
Section 3 - Composition/Information on Ingredients
Product Name & Other Names: Glacial Acetic Acid or Ethanoic acid or Ethylic acid or Methanecarboxylic acid or Vinegar.
CAS#: 64-19-7
EINECS EC Number: 200-580-7
Percent: 99-100% on dry basis. Dilution is always with water.
Section 4 - First Aid Measures
Always consult a physician after the first aid is given.
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Do NOT allow victim to rub or keep eyes closed.
Skin: Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion: Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician: Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Flammability: Flammable. Explosive in presence of oxidizing materials.
Flash Point: 40C 104F
Auto Ignition Temperature: 463C 865F
Extinguishing Media: Use DRY chemical powder, alcohol foam, water spray or fog. Cool containing vessels with water jet to prevent pressure build-up, auto-ignition, or explosion.
Extinguishing Media Not recommended: Avoid using solid water jet as it may scatter the fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used.
Section 6 - Accidental Release Measures
Personal precautions, protective equipment, and emergency procedures: Ventilate area of leak or spill. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.).Do not approach facing the wind.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate as per law. Remove all ignition sources and ventilate area. Neutralize with sodium bicarbonate or calcium hydroxide or dry soda ash or calcium carbonate and deposit in a sealed bag or container. Use water spray to dilute spill to a non-flammable mixture. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation.
Section 7 - Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust/mist generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.).
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, strong alkalis, and metals. Store protected from heat and flames.
Section 8 - Exposure Controls, Personal Protection
Airborne Exposure Limits:
USA OSHA Permissible Exposure Limit (PEL): 10 ppm (TWA).
ACGIH Threshold Limit Value (TLV): 10 ppm (TWA); 15 ppm (STEL).
USA NIOSH 10ppm TWA; 25 mg/m3 TWA 50ppm IDLH
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice.
Section 9 - Physical and Chemical Properties
Appearance: Clear Liquid
Odor: Vinegar odor
Odor threshold: Not available.
pH: 2 for 1% solution, 2.4 (1.0M solution)
Relative density: around 1.05
Boiling Point: 118C (244.5F)
Melting Point: 16.6C (61.9F).
Flash point: Not available.
Auto-ignition temperature: No information found.
Decomposition temperature: No information found.
Upper/lower flammability or explosive limits: No information found.
Vapor pressure: No information found.
Vapor density: No information found.
Evaporation rate: No information found.
Flammability (solid, gas): No information found.
Partition coefficient: n-octanol/water: No information found.
Solubility: Soluble in water
Viscosity: No information found.
Molecular Formula: C2H4O2
Molecular Weight: 60.05
Section 10 - Stability and Reactivity
Chemical Stability: Stable under normal temperatures and pressures. It is hygroscopic.
Conditions to Avoid: Incompatible materials, dust/mist generation, moisture, exposure to heat, spark, moist air, or water.
Incompatibilities with Other Materials: Oxidizing agents, strong alkalis, and metals.
Hazardous Decomposition Products: Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Will not occur.
Section 11 - Toxicological Information
Acute oral toxicity (LD50): 3310 mg/kg [Rat].
Acute dermal toxicity (LD50): 1060 mg/kg [Rabbit].
Acute toxicity of the vapor (LC50): 5620 1 hours [Mouse].
LC50 Inhalation - rat - 4 h - 11.4 mg/l 4 hours
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Mutagenic Effects: No information found.
Teratogenic Effects: No information found.
Developmental Toxicity: No information found.
Reproductive Effects: No information found.
Section 12 - Ecological Information
Persistence and Degradability: The material will readily biodegrade.
Mobility: Mobile due to water solubility
Bioaccumulation/ Accumulation: Unlikely to bioaccumulate
Results of PBT and vPvB assessment: No data available for assessment.
Toxicity: (LC50): 423 mg/l 24 hours [Fish (Goldfish)]. 88 ppm 96 hours [Fish (fathead minnow)]. 75 ppm 96 hours [Fish (bluegill sunfish)]. >100 ppm - 96 hours [Daphnia].
Section 13 - Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility.
Section 14 - Transport Information
Road Transport DOT USA, TDG Canada and ADR/RID Europe
UN number: 2789
Class: 8 (3)
Packing group: II
Proper shipping name: Acetic acid, glacial
Sea Transport IMDG/IMO
UN number: 2789
Class: 8 (3)
Packing group: II
Proper shipping name: Acetic acid, glacial
Air Transport IATA/ICAO
UN number: 2789
Class: 8 (3)
Packing group: II
Proper shipping name: Acetic acid, glacial.
Section 15 - Regulatory Information
USA:
SARA 311/312 Hazards: Acute Health Hazard, Chronic Health Hazard.
California Prop. 65 Components: Not listed to cause cancer, birth defects, or any other reproductive harm.
Section 16 - Additional Information
DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources, and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules, or insurance requirements applicable. This SDS MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a professionally trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. This shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. In no case shall our company be liable to loss or damages by the product user.
Acetic Acid Solution SDS, Safety Data Sheet
MSDS, Material Safety Data Sheet 13-Aug-22
Section 1 - Chemical Product and Company Identification
Product Name & Other Names: Acetic Acid Solution
Synonyms: Ethanoic acid solution, Ethylic acid solution, Vinegar.
Molecular Weight: 60.05
Molecular Formula: CH3COOH
Relevant uses and uses advised against (if any): Oil & Gas Fracturing and Industrial Manufacturing.
Suppliers: As per letterhead.
Section 2 - Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Flammable liquids (Category 3) H227
Skin corrosion/irritation (Category 1A, B, C) H314
Acute aquatic toxicity (Category 3) H402
Labeling according GHS & Regulation (EC) No 1272/2008
GHS Label Elements
Corrosive |
Signal Words: Danger
Hazard statements:
H314: Causes severe skin burns and eye damage.
H402: Harmful to aquatic life.
Precautionary statements:
P210: Keep away from heat, sparks, open flames, hot surfaces. - No smoking.
P233: Keep container tightly closed.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical, ventilating, lighting equipment.
P242 - Use only non-sparking tools.
P243: Take precautionary measures against static discharge.
P260: Do not breathe mist, vapors, spray.
P264: Wash exposed skin thoroughly after handling.
P280: Wear protective clothing, protective gloves, eye protection, face protection.
P301+P330+P331: IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303+P361+P353: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
P304+P340: IF INHALED: remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P310: Immediately call a POISON CENTER or doctor/physician.
P314: Get Medical advice/attention if you feel unwell.
P337+ P313 If eye irritation persists: Get medical advice/ attention.
P360: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P363: Wash contaminated clothing before reuse.
P370+P378: In case of fire: Use carbon dioxide (CO2), powder, alcohol-resistant foam for extinction.
Section 3 - Composition/Information on Ingredients
Chemical Name: Acetic Acid Solution
CAS#: 64-19-7
EINECS EC Number: 200-580-7
Percent: 30% to 80% on dry basis or as specified by the buyer. Dilution is always with water
Section 4 - First Aid Measures
Always consult a physician after the first aid is given.
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid. Do NOT allow victim to rub or keep eyes closed.
Skin: Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists. Wash clothing before reuse.
Ingestion: Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupful of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician: Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion.
Flash Point: 40C 104F for glacial material.
Auto Ignition Temperature: 463C 865F for glacial material.
Extinguishing Media: Use DRY chemical powder, alcohol foam, water spray or fog. Cool containing vessels with water jet to prevent pressure build-up, auto-ignition, or explosion.
Section 6 - Accidental Release Measures
Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Do not approach facing the wind.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage: Use proper personal protective equipment. Restrict unprotected personnel from the area. Remove all ignition sources and ventilate area. Contain the spill with sand or other inert absorbent material, neutralize with sodium bicarbonate or calcium hydroxide, and deposit in a sealed bag or container. Avoid runoff into storm sewers and ditches which lead to waterways. Wash area with soap and water. Use water spray to disperse the gas/vapor. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. Cover with material such as dry soda ash or calcium carbonate and place into a closed container for disposal.
Section 7 - Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.).
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like oxidizing agents, strong alkalis, and metals. Store protected from heat and flames.
Section 8 - Exposure Controls, Personal Protection
Airborne Exposure Limits:
OSHA Permissible Exposure Limit (PEL): 10 ppm (TWA) for glacial material.
ACGIH Threshold Limit Value (TLV): 10 ppm (TWA); 15 ppm (STEL)for glacial material.
NIOSH 10ppm TWA; 25 mg/m3 TWA 50ppm IDLH for glacial material.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator (NIOSH type N95 or better filters) may be worn.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.
Section 9 - Physical and Chemical Properties
Appearance: Clear Liquid
Odor: Vinegar odor
Odor threshold: Not available.
pH: 2 for 1% solution, 2.4 (1.0M solution)
Relative density: 1.049 for glacial material.
Boiling Point: 118C (244.5F) for glacial material.
Melting Point: 16.6C (61.9F) for glacial material.
Flash point: Not available.
Auto-ignition temperature: No information found.
Decomposition temperature: No information found.
Upper/lower flammability or explosive limits: No information found.
Vapor pressure: No information found.
Vapor density: No information found.
Evaporation rate: No information found.
Flammability (solid, gas): No information found.
Partition coefficient: n-octanol/water: No information found.
Solubility: Soluble in water
Viscosity: No information found.
Molecular Formula:C2H4O2 for glacial material.
Molecular Weight:60.05 for glacial material.
Section 10 - Stability and Reactivity
Chemical Stability: Acetic acid solution is stable under normal temperatures and pressures. It is hygroscopic.
Conditions to Avoid: Incompatible materials, dust generation, moisture, exposure to heat, spark, moist air or water.
Incompatibilities with Other Materials: Oxidizing agents, strong alkalis and metals.
Hazardous Decomposition Products: Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Will not occur.
Section 11 - Toxicological Information
Acute oral toxicity (LD50): 16550 mg/kg (Rat).
Acute oral toxicity (LD50): 3310 mg/kg [Rat] for Glacial Material.
Acute dermal toxicity (LD50): 1060 mg/kg [Rabbit] for Glacial Material.
Acute toxicity of the vapor (LC50): 5620 1 hours [Mouse] for Glacial Material.
LC50 Inhalation - rat - 4 h - 11.4 mg/l 4 hours.
Carcinogenicity: The material is not reported as a carcinogen.
Mutagenic Effects: No information found.
Developmental Toxicity: No information found.
Reproductive Effects: No information found.
Section 12 - Ecological Information
Environmental Fate: The material will readily biodegrade.
Environmental Toxicity: (LC50): 423 mg/l 24 hours [Fish (Goldfish)]. 88 ppm 96 hours [Fish (fathead minnow)]. 75 ppm 96 hours [Fish (bluegill sunfish)]. >100 ppm - 96 hours [Daphnia] for glacial material.
Mobility: Likely to be mobile.
Results of PBT and vPvB assessment: No information found.
Section 13 - Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility.
Section 14 - Transport Information
DOT USA & ADR/RID Europe
UN number: 2790
Class: 8; Packing group: II
Proper shipping name: Acetic acid, solution
Reportable Quantity (RQ): 6250 lbs
Marine pollutant: No
IMDG
UN number: 2790
Class: 8; Packing group: II
Proper shipping name: Acetic acid, solution
Reportable Quantity (RQ): 6250 lbs
Marine pollutant: No
IATA
UN number: 2790
Class: 8; Packing group: II
Proper shipping name: Acetic acid, solution
Reportable Quantity (RQ): 6250 lbs
Section 15 - Regulatory Information
USA:
California Prop. 65 Components: Not listed to cause cancer, birth defects, or any other reproductive harm.
Section 16 - Additional Information
DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.
Specifications of Acetic Acid Solution n Acetic Acid Glacial BP Ph Eur EP JP USP NF IP ACS Analytical Reagent FCC Food grade Manufacturers |
