Aluminum Chloride Hexahydrate or Aluminium Chloride Hexahydrate SDS MSDS of Manufacturers & Exporters, also Aluminum Chloride Anhydrous or Aluminium Chloride Anhydrous
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Aluminum Chloride Hexahydrate or Aluminium Chloride Hexahydrate CAS Number 7784-13-6
Aluminum Chloride Anhydrous or Aluminium Chloride Anhydrous CAS Number 7446-70-0
Aluminum Chloride Hexahydrate or Aluminium Chloride Hexahydrate
SDS, Safety Data Sheet
MSDS, Material Safety Data Sheet 22-July-22
1. Product Identification
Product Name & Other Names: Aluminum Chloride Hexahydrate or Aluminium Chloride Hexahydrate or Aluminum trichloride hexahydrate or Trichloro aluminum hexahydrate
CAS Number: 7784-13-6
EINECS: EC Number: 231-208-1
Chemical Formula: AlCl3-6H2O
Molecular Weight: 241.43
Recommended usage: Industrial Manufacturing.
Suppliers: As per letterhead.
2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008:
Acute toxicity, Oral (Category 5), H303
Skin corrosion/irritation (Category 2), H315
Serious eye damage/eye irritation (Category 2A), H319
Specific target organ toxicity - single exposure (Category 3), H335
Acute aquatic toxicity (Category 3), H402
Labeling according to GHS & Regulation (EC) No 1272/2008
GHS Label Elements
Irritant |
Signal Words: Warning
Hazard statements:
H303: May be harmful if swallowed.
H315: Causes skin irritation.
H319: Causes serious eye irritation.
H335: May cause respiratory irritation.
H402: Harmful to aquatic life.
Precautionary statements:
P261: Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P262: Do not get in eyes, on skin, or on clothing.
P264 Wash skin thoroughly after handling.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330 + P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P302+P352 IF ON SKIN: Wash with plenty of soap and water.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P332+313: If skin irritation occurs: Get medical advice/attention.
P314: Get Medical advice/attention if you feel unwell.
3. Composition/Information on Ingredients
Product Name & Other Names: Aluminum Chloride Hexahydrate or Aluminium Chloride Hexahydrate or Aluminum trichloride hexahydrate or Trichloro aluminum hexahydrate.
CAS Number: 7784-13-6
EINECS: EC Number: 231-208-1
4. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Note to Physician: Treat symptomatically.
5. Fire Fighting Measures
Flammability of the Product: The product is not flammable.
Products of Combustion: It forms oxides of aluminum and hydrochloric acid when heated to decomposition.
Fire Extinguishing Media: Use water spray, dry chemical, foam, or carbon dioxide.
Extinguishing Media Not recommended: Avoid using solid water jet as it may scatter the fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.
6. Accidental Release Measures
Personal precautions, protective equipment, and emergency procedures: Ventilate area of leak or spill. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment cleanup procedures and Storage:
Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g., sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to legal requirements.
7. Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Keep container tightly closed. Avoid ingestion and inhalation. Avoid formation of dust and aerosols. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, alkalis, and moisture.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits: None established. Assure it as below 2mg/m3.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full-face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.
9. Physical and Chemical Properties
Appearance: Crystals or powder or granules.
Odor: Mild typical.
Odor threshold: Not available.
pH: Not available.
Relative density: around 2.4
Melting Point: 100C
Initial boiling point and boiling range: Not available.
Flash point: Not available.
Auto-ignition temperature: No information found.
Decomposition temperature: No information found.
Upper/lower flammability or explosive limits: No information found.
Vapor pressure: No information found.
Vapor density: No information found.
Evaporation rate: No information found.
Flammability (solid, gas): No information found.
Partition coefficient: n-octanol/water: No information found.
Solubility: Readily soluble in water.
Viscosity: No information found.
Molecular Weight: 241.43
Molecular Formula: AlCl3-6H2O
10. Stability and Reactivity
Stability: Stable under ordinary conditions of use and storage. It must be kept in air-tight containers.
Hazardous Decomposition Products: It produces oxides of aluminum along with hydrochloric acid when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Incompatible with water including moisture, oxidizing material and alkalis.
Conditions to Avoid: Moisture, Heat, Sun light, Incompatibles.
11. Toxicological Information
Toxicity to Animals:
Oral, mouse: LD50 = 1990 mg/kg;
Oral, rat: LD50 = 3311 mg/kg;
Carcinogenic Effects: Not a reported carcinogen.
Mutagenic Effects: No information found.
Teratogenic Effects: No information found.
Developmental Toxicity: No information found.
12. Ecological Information
Environmental Toxicity:
Toxicity to fish: LC50 - fish - 27.1 mg/l - 96 h
Toxicity to daphnia and other aquatic invertebrates: EC50 - Daphnia magna (Water flea) - 27.3 mg/l - 48 h
Persistence and Degradability: No information found.
Mobility: No information found.
Bioaccumulation/ Accumulation: No information found.
Results of PBT and vPvB assessment: No information found.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused Aluminum chloride Hexahydrate in accordance with federal, state, and local requirements.
14. Transport Information
Road Transport DOT USA, TDG Canada & ADR/RID Europe: Not Regulated.
Sea Transport IMDG/IMO: Not Regulated.
IATA/ICAO: Not Regulated.
15. Regulatory Information
USA:
SARA 311/312 Hazards: Acute Health Hazard. See section 2.
California Prop 65: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
16. Other Information
DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources, and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules, or insurance requirements applicable. This SDS MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a professionally trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. This shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. In no case shall our company be liable to loss or damages by the product user.
Aluminum Chloride Anhydrous SDS, Safety Data Sheet Aluminium Chloride Anhydrous
MSDS, Material Safety Data Sheet 22-July-22
1. Product Identification
Product Name & Other Names: Aluminum Chloride Anhydrous or Aluminium Chloride Anhydrous or Aluminum trichloride or Trichloro aluminum.
CAS No.: 7746-70-0
EINECS: EC Number: 231-208-1
Molecular Weight: 133.34
Chemical Formula: AlCl3
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead above.
2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008:
Acute toxicity, oral Category 5, H303
Skin corrosion/irritation Category 1A, B, C, H314
Specific target organ toxicity – repeated exposure, Inhalation Category 1, H372
Hazardous to the aquatic environment, acute hazard Category 3, H402
Labeling according to GHS & Regulation (EC) No 1272/2008
GHS Label Elements
Health Hazard |
GHS Label Elements
Corrosive |
Signal Words: Danger
Hazard statements:
H303: May be harmful if swallowed.
H314: Causes severe skin burns and eye damage.
H372: Causes damage to organs through prolonged or repeated exposure.
H402: Harmful to aquatic life.
Precautionary statements:
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P261: Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P262: Do not get in eyes, on skin, or on clothing.
P264 Wash skin thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P301 + P330 + P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303 + P361 + P352 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Wash with plenty of soap and water.
P304 + P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314: Get Medical advice/attention if you feel unwell.
P337+P313: If eye irritation persists: Get medical advice/ attention.
P263: Avoid contact during pregnancy/while nursing.
Other hazards which do not result in classification: Reacts violently with water.
3. Composition/Information on Ingredients
Product Name & Other Names: Aluminum Chloride Anhydrous or Aluminium Chloride Anhydrous or Aluminum trichloride or Trichloro aluminum.
CAS No.: 7746-70-0
EINECS: EC Number: 231-208-1
4. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: Wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
Note to Physician: Treat symptomatically.
5. Fire Fighting Measures
Flammability of the Product: The product is not flammable.
Flash Points: NA.
Products of Combustion: It forms oxides of aluminum and hydrochloric acid when heated to decomposition.
Fire Extinguishing Media: Use dry chemical, foam, or carbon dioxide.
Extinguishing Media Not recommended: Avoid using water and solid water jet.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used. Uninvolved persons should evacuate to a safe place.
6. Accidental Release Measures
Personal precautions, protective equipment, and emergency procedures: Ventilate area of leak or spill. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Restrict unprotected personnel from the area. Prevent any contact with hot surfaces. Do not approach facing the wind. Do not touch the spilled material.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment cleanup procedures and Storage: Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g., sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container.
7. Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Prevent any contact with hot surfaces.
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like strong oxidizing agents, water, ethylene oxide, oxygen difluoride, phenols, nitro compounds, perchloryl fluoride, benzene. Avoid moisture and store away from water sources. It is to be stored in corrosive area.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits: None established. Assure it as below 2mg/m3.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full-face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.
9. Physical and Chemical Properties
Appearance: Yellowish crystals or powder or granules.
Odor: Typical
Odor threshold: Not available.
pH: Not available.
Relative density: around 2.45
Boiling Point: Sublimes.
Melting Point: Sublimes.
Flash point: Not available.
Auto-ignition temperature: No information found.
Decomposition temperature: No information found.
Upper/lower flammability or explosive limits: No information found.
Vapor pressure: No information found.
Vapor density: No information found.
Evaporation rate: No information found.
Flammability (solid, gas): No information found.
Partition coefficient: n-octanol/water: No information found.
Solubility: Readily soluble in water and it reacts with it.
Viscosity: No information found.
Molecular Weight: 133.34
Molecular Formula: AlCl3
10. Stability and Reactivity
Stability: Stable under ordinary conditions of use and storage. It must be kept in air-tight containers.
Hazardous Decomposition Products: It produces oxides of aluminum along with hydrochloric acid when heated to decomposition.
Hazardous Polymerization: Will not occur.
Incompatibilities: Reacts with metals and water including moisture. Water, ethylene oxide, oxygen difluoride, phenols, nitro compounds (organic, e.g., nitrobenzene, nitroglycerine, picric acid, trinitrotoluene), perchloryl fluoride, benzene are reported incompatibles.
Conditions to Avoid: Moisture, Heat, Sun light, Incompatibles.
11. Toxicological Information
Toxicity to Animals:
Skin, rabbit: LD50 = >2000 mg/kg;
Oral, mouse: LD50 = 1130 mg/kg;
Oral, rat: LD50 = 3450 mg/kg;
Carcinogenic Effects: Not a reported carcinogen.
Mutagenic Effects: It may have mutagenic effect.
Teratogenic Effects: No information found.
12. Ecological Information
Toxicity to fish:
LC50 - Carassius auratus (goldfish) - 0.15 mg/l - 7 d
LC50 - Oncorhynchus mykiss (rainbow trout) - 7 mg/l - 96 h
Toxicity to daphnia and other aquatic invertebrates:
EC50 - Daphnia magna (Water flea) - 3.9 mg/l - 48 h
Persistence and Degradability: No information found.
Mobility: No information found.
Bioaccumulation/ Accumulation: No information found.
Results of PBT and vPvB assessment: No information found.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations.
14. Transport Information
Land Transport DOT USA, TDG Canada & ADR/RID Europe:
UN-Number: 1726 Class: 8 Corrosive Material Packing group: II
Proper shipping name: Aluminum Chloride Anhydrous
Marine pollutant: No
Poison Inhalation Hazard: No
Sea Transport IMDG/IMO:
UN-Number: 1726 Class: 8 Corrosive Material Packing group: II; -- EMS-No: F-A, S-Q
Proper shipping name: Aluminum Chloride Anhydrous
Marine pollutant: No
Air Transport IATA/ICAO:
UN-Number: 1726 Class: 8 Corrosive Material Packing group: II
Proper shipping name: Aluminum Chloride Anhydrous.
15. Regulatory Information
USA:
SARA 311/312 Hazards: See section 2.
California Prop 65: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.
16. Other Information
DISCLAIMER: The information and recommendations set forth herein are presented in good faith and believed correct as of the date hereof. It is compiled from various sources, and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules, or insurance requirements applicable. This SDS MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a professionally trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. This shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. In no case shall our company be liable to loss or damages by the product user.
Specifications of Aluminum Chloride Hexahydrate or Aluminium Chloride Hexahydrate BP Ph Eur EP JP USP NF IP ACS Analytical Reagent FCC Food grade Manufacturers |
