Glutaraldehyde or Glutaral Concentrate SDS MSDS of Manufacturers & Exporters
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Glutaraldehyde or Glutaral Concentrate CAS Number 111-30-8
Glutaraldehyde Glutaral Concentrate Glutaric acid dialdehyde
SDS, Safety Data Sheet
MSDS Sheet, Material Safety Data Sheet 15-Aug-22
1. Product Identification
Product Name & Other Names: Glutaraldehyde Glutaral Concentrate Glutaric acid dialdehyde.
CAS No.: 111-30-8
EINECS EC Code: 203-856-5
Molecular Weight: 100.12 for un-diluted material.
Chemical Formula: CH2(CH2CHO)2 for un-diluted material.
Relevant uses and uses advised against (if any): Oil & Gas Wells fracturing and Industrial Manufacturing.
Suppliers: As per letterhead.
2. Hazards Identification
GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008
Acute toxicity, Oral (Category 4), H302
Skin corrosion (Sub-category 1B), H314
Acute toxicity, Inhalation (Category 3), H331
Skin sensitization (Category 1), H317
Respiratory sensitization (Category 1) H334
Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335
Long-term (chronic) aquatic hazard (Category 1), H410
Labeling according to GHS USA & Regulation (EC) No 1272/2008
GHS Label Elements
Toxic |
GHS Label Elements
Corrosive |
GHS Label Elements
Health Hazard |
GHS Label Elements
Aquatic Toxicity |
Signal Word: Danger
Hazard Statements:
H302: Harmful if swallowed
H314: Causes severe skin burns and eye damage.
H317: May cause an allergic skin reaction
H331: Toxic if inhaled
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H410: Very toxic to aquatic life.
Precautionary Statements
P220: Keep/Store away from clothing/other combustible materials.
P221: Take any precaution to avoid mixing with combustibles.
P234 Keep only in original container.
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash ... thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280-Wear protective gloves/protective clothing/eye protection/face protection.
P284 Wear respiratory protection.
P301+P310+330: IF SWALLOWED: Rinse mouth and immediately call a POISON CENTER or doctor/physician.
P302+P352: IF ON SKIN: Wash with soap and water.
P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P304 + P341 + P311 IF INHALED: If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P332+P313: If skin irritation occurs: Get medical advice/attention.
P314: Get Medical advice/attention if you feel unwell.
P330: If swallowed, rinse mouth.
P337+P313 If eye irritation persists: Get medical advice/ attention.
3. Composition/Information on Ingredients
Product Name & Other Names: Glutaraldehyde Glutaral Concentrate Glutaric acid dialdehyde.
CAS No.: 111-30-8
EINECS EC Code: 203-856-5
Percentage: 10% to 70%
4. First Aid Measures
Always seek medical attention after first aid measures are provided.
Inhalation: If Glutaraldehyde is inhaled, it will cause irritation and damage to nose and throat. It can cause headache, bleeding from nose coughing and chest discomfort. Remove the victim to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.
Ingestion: It will cause irritation and burns to mouth, digestive tract and stomach. It may lead to pain, nausea, vomiting, and even collapse. Contact medical center quickly. Never give anything by mouth to an unconscious person. Get medical attention.
Skin Contact: On contact, it can cause itching, pain, swelling and redness. Immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eye Contact: It can cause severe damage to eyes. Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Cold water may be used. Get medical attention.
5. Fire Fighting Measures
Fire: Flash point: NA.
Toxic fumes, carbon dioxide and carbon monoxide may be formed in fire.
Explosion: Not known.
Fire Extinguishing Media: Dry chemical, foam or carbon dioxide and water spray jet.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used.
6. Accidental Release Measures
Personal precautions, protective equipment, and emergency procedures: Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Do not approach facing the wind.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment Cleanup procedures and Storage:
Small Spill: Mop and pick up the material and place in an appropriate waste disposal container.
Large Spill: Avoid mist formation. Keep away from heat. Keep away from sources of ignition. The concentration of Glutaraldehyde can be brought down by neutralizing with 1.25 moles of Diammonium Phosphate. Do not inhale dust, vapors, mist, or gas. Avoid dust formation. Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite). Use a shovel to put the material into a convenient waste disposal container.
7. Handling and Storage
Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Keep container tightly closed. Avoid ingestion and inhalation. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.).
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Avoid contact with skin and eyes. Avoid inhalation of dust/mist/vapor. Do not store with incompatible materials like metals, strong acids & alkalis, oxidizing & reducing agents. Do not allow to freeze. Avoid contact. Do not store near food items or near Diammonium Phosphate.
8. Exposure Controls/Personal Protection
Airborne Exposure Limits: TWA: Long term (8 hours) & Short term(15 minutes) WEL is 0.05 ppm.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to the substance is apparent and engineering controls are not feasible, consult an industrial hygienist. including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice. Wash hands after handling.
9. Physical and Chemical Properties
Appearance: Colorless liquid.
Odor: Typical aldehyde smell.
Odor threshold: Not available.
pH: Not available.
Relative density: 1.025 approximate.
Melting point/freezing point: Not available.
Boiling Point: >100C
Flash point: Not available.
Auto-ignition temperature: No information found.
Decomposition temperature: No information found.
Upper/lower flammability or explosive limits: No information found.
Vapor pressure: No information found.
Vapor density: No information found.
Evaporation rate: No information found.
Flammability (solid, gas): No information found.
Partition coefficient: n-octanol/water: No information found.
Solubility: miscible with water
Viscosity: No information found.
Molecular Weight: 100.12 for un-diluted material.
Molecular Formula: CH2(CH2CHO)2 for un-diluted material.
10. Stability and Reactivity
Stability: Glutaraldehyde is stable under ordinary conditions of use and storage.
Hazardous Decomposition Products: Carbon dioxide, carbon monoxide and toxic fumes may form when heated to decomposition.
Hazardous Polymerization: Not reported.
Incompatibilities: Metals, strong acids & alkalies, oxidizing & reducing agents, heat and sparks.
Conditions to Avoid: Heat, flames, ignition sources and incompatibles.
11. Toxicological Information
Oral rat LD50: 134 mg/kg.
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Teratogenic Effects: No information found.
Mutagenic Effects: No information found.
Developmental Toxicity: No information found.
Reproductive Effects: No information found.
12. Ecological Information
Environmental Toxicity: Toxic to fish and aquatic life.
Persistence and Degradability: The product is easily biodegradable.
Mobility: Likely to be mobile due to water solubility.
Bioaccumulation/ Accumulation: No information found.
Results of PBT and vPvB assessment: No information found.
13. Disposal Considerations
Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility.
14. Transport Information
DOT USA, TDG Canada & ADR/RID Europe
UN Number: 2922
Proper shipping name: Corrosive liquid, acidic, organic. NOS (contains glutaraldehyde)
Class: 8 (6.1), Packing group: II
IMDG/IMO & IATA/ICAO
UN Number: 2922
Proper shipping name: Corrosive liquid, acidic, organic. NOS (contains glutaraldehyde)
Class: 8 (6.1), Packing group: II.
15. Regulatory Information
USA:
SARA 311/312: Acute & Chronic hazards.
California Prop 65: Not listed.
Section 16 - Additional Information
European Labeling in Accordance with EC Directives:
H302: Harmful if swallowed
H314: Causes severe skin burns and eye damage.
H317: May cause an allergic skin reaction
H331: Toxic if inhaled
H334: May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H335 May cause respiratory irritation.
H410: Very toxic to aquatic life.
DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules, or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a professionally trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.
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